Transition metal chalcogenides
(compounds based on sulfur, selenium or tellurium) have long been known
and explored. Due to their reduced dimensionality, such compounds
sometimes display charge density wave (CDW) transitions or, upon doping
with magnetic ions, often reveal dramatic changes of their physical
properties. I will discuss two different effects due to
transition metal intercalation on the properties of layered
chalcogenide materials, TiSe2 and TaS2.
Although TiSe2 is one of the first known CDW-bearing
materials, the nature of its CDW transition remains
controversial. Recently the interest in TiSe2 has been
renewed by our discovery of the new superconducting state (SC) that
emerges upon Cu doping. Thus CuxTiSe2
provides the first example of a system in which controlled chemical
doping can be used to study the competition between the CDW and
SC. When Cu is intercalated between the layers of TaS2,
a CDW-to-SC transition is also observed, although the origin of this
transition is apparently different in the two compounds, and I will
point out the similarities and differences between CuxTiSe2 and CuxTaS2. I will also
discuss experiments on Fe-doped TaS2 aimed at studying the
sharp switching of the magnetization that we observed in FexTaS2 for x = 1/4. For this particular
Fe content, FexTaS2
orders ferromagnetically below 160 K and displays very sharp hysteresis
loops in the ordered state when the applied field is perpendicular to
the TaS2 layers. The corresponding magnetoresistance is
negative, and qualitatively reproduces the features observed in the M(H)
data, by showing a sharp drop around the critical field for moment
reversal.