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Diffraction as a tool to determine crystal structures

Diffraction is not only a fascinating phenomenon for physicists to marvel about but it is in fact the only way we have to determine the atomic structure of solids. In solids atoms are spaced by distances of order tex2html_wrap_inline229 m and it is not possible to resolve the atomic locations using a conventional microscope. Instead we use diffraction of waves that have wave lengths of order the atomic spacing. Electromagnetic waves with such short wave lengths are called X-rays. When X-rays illuminate a crystal each atom subject to the radiation becomes a point source of X-rays as it oscillates in synchronization with the local electric field from the incident X-ray beam. Constructive and destructive interference occurs only under the very special conditions wherein X-rays reflected by a finite fraction of atoms in the crystal add in phase. Fig. 3 shows a situation in which waves from all atoms undergo constructive interference. The lines tilted lines shown signify normals to the wave fronts of the incident and scattered X-ray beams. The path difference for these beams is
equation91
The condition for constructive interference is thus
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Thus from measuring the diffraction angles when X-rays reflect from a periodic crystal structure we can determine the spacing between atoms in solids. I show examples of X-ray diffraction from a single crystal (Laue diffraction with ``white'' X-ray beam) and neutron diffraction from a sample with a large number of crystals oriented at random.



Collin Broholm
Mon Nov 17 22:56:19 EST 1997