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Adiabatic free expansion

An adiabatic free expansion of an ideal gas ie. where a greater volume suddenly becomes available to the gas is an irreversible process which proceeds through a chaotic non-equilibrium path. Nonetheless we can characterize the beginning and end points and the net values of relevant changes in energy. Since the gas expands against a vacuum it does no work and thus
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combining this with our requirement that the process is adiabatic we have
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If we are dealing with an ideal gas then the absence of a change in the internal energy implies that the temperature is the same before and after the expansion even though no temperature is defined during the irreversible process. Using the equation of state for an ideal gas this implies that
equation141
Note the similarity to the result for an adiabatic reversible process with the important difference of the power tex2html_wrap_inline329 and the corresponding change in temperature which occurs only in the adiabatic reversible process.



Collin Broholm
Wed Nov 26 17:12:00 EST 1997