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Collision and transport phenomena

As a result of thermal motion there is an inherent transport of molecules through a gases and liquids in thermal equilibrium. This is as opposed to solids in which atoms generally stay but at a specific site of the lattice. Here we shall focus on transport in gases and shall set ourselves the task of calculating how fast atoms or molecules diffuse through a gas.

As we realized in a previous numerical example the motion of individual atoms in a gas at room temperature is actually quite fast, typically 1000 m/s. However the effective transport velocity is considerably slower because of the constant collision between individual atoms. If we denote the cross sectional area of an atom by tex2html_wrap_inline267 then it can be shown the mean time between collisions is
equation112
Correspondingly the mean distance traveled between collisions is
equation117
for the cross section we typically use
equation122
where r is a characteristic radius of the atom. The factor 2 comes from realizing that the atoms can be separated up to a distance 2r and still collide! Inserting
equation124
and
equation131
we get
eqnarray141
So collisions occur often and distances traversed between collisions is small. Not however that the distances traversed are very large compared to the size of a single atom and this is what makes it possible to neglect collisions for the purpose of calculating the pressure exerted by the gas. The motion of an individual atom is diffusive and it can be shown that in a time t it progresses a distance
equation151
Based on the values derived for tex2html_wrap_inline275 and tex2html_wrap_inline277 we calculate the time taken for atoms to diffuse from one end of the auditorium to the other:
equation157
putting in numbers we get
equation161
A surprisingly long time indeed. Clearly we rely on convection to spread the smells of perfume etc. Note however that even though no single molecule moves very far, thermal equilibrium is spread at a speed close to the speed of sound in the gas because energy travels through the system in waves at that speed.


next up previous
Next: About this document Up: Microscopic description of the Previous: Calorimetry demonstration experiment

Collin Broholm
Tue Dec 2 09:59:31 EST 1997