states: that if a system undergoes a change from one equilibrium state to another, the difference between the heat
supplied to the system and the work
done by the system will depend only on the initial and final equilibrium states and not on the process by which the change is brought about. [P7.3, P7.4, P7.5]
justifies: the introduction of a function of state known as the internal energy
which changes by an amount
in the process. [P7.3, P7.4, P7.5]
represents: the conservation of energy, but also has an additional implication. Because
and
are not functions of state, their respective contributions to
cannot be disentangled, and it does not generally make sense to speak of the 'heat content' of a system. [P7.3, P7.4, P7.5]
Copyright 1997, The Open University