The previously-described band structure is important for
determining the conductivity of the material. This is due to the
Fermi energy and where it lies on the band structure.
At everyday temperatures, the Fermi level blurs a bit due to the
Fermi-Dirac distribution, but the Fermi energy itself can
typically be used to estimate the conductivity.
For elements with an even number of valence electrons, the
Fermi energy lies in the gap between energy bands. This implies
that a significant amount of energy the size of the gap must be
added to the system to insert another electron. This inserted
electron would give rise to conductivity, but is difficult if it
has to overcome the energy gap. These materials are
insulators,
because it requires significant energy to get a current flow.
However, materials with an odd number of valence electrons have the
Fermi energy halfway in each band. That is, the Fermi energy
does not lie in a gap. To insert another electron, only a small
amount of energy is required, equal to the spacing between the
quasi-continuous energy levels. These materials are
conductors.
A third class of materials exists, which should be classified as
insulators. However, the band gap is small enough that thermal
excitation gives the electrons enough energy to jump the band, and
they give rise to some current. These materials are
semi-conductors.